Here are the countries participating in the second semi-final, in order of appearance:
- Iceland: Eurobandið – “This Is My Life”
- Sweden: Charlotte Perrelli – “Hero”
- Turkey: Mor Ve Otesi – “Deli”
- Ukraine: Ani Lorak – “Shady Lady”
- Lithuania: Jeronimas Milius – “Nomads In the Night”
- Albania: Olta Boka – “Zemrën Lamë Peng”
- Switzerland: Paolo Meneguzzi -“Era Stupendo”
- Czech Republic: Tereza Kerndlová – “Have Some Fun”
- Belarus: Ruslan Alekhno – “Hasta la Vista”
- Latvia: Pirates of the Sea – “Wolves of the Sea”
- Croatia: Kraljevi Ulice & 75 Cents – “Romanca”
- Bulgaria: Deep Zone & Balthazar – “DJ, Take Me Away”
- Denmark: Simon Mathews – “All Night Long”
- Georgia: Diana Gurtskaya – “Peace Will Come”
- Hungary: Csézy – “Szívverés”
- Malta: Morena – “Vodka”
- Cyprus: Evdokia Kadi – “Femme Fatale”
- FYR Macedonia: Tamara Todevska, Vrčak & Adrian Gadza – “Vo Imeto Na Ljubovta”
- Portugal: Vânia Fernandes – “Senhora do Mar”